Diaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN 3}dichloridocadmium hexahydrate
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چکیده
منابع مشابه
1H-Benzimidazol-2-ylmethyl phenyl ether
There are two mol-ecules in the asymmetric unit of the title compound, C(14)H(10)N(2)O: the dihedral angles between their aromatic ring planes are 47.4 (4) and 46.8 (3)°. In the crystal structure, mol-ecules are linked by N-H⋯N hydrogen bonds from the secondary nitro-gen N-H donor to the tertiary N-atom acceptor of a symmetry-related neighbour, resulting in hydrogen-bonded chains. The two indep...
متن کاملDiaquabis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN 3}dichloridocadmium hexahydrate
In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial positions, leading to an elongated octa-hedral environment. The two coordinating and two of the latti...
متن کاملBis[N,N-bis(1-allyl-1H-benzimidazol-2-ylmethyl-κN 3)benzylamine-κN]cadmium dipicrate
The crystal structure of the title compound, [Cd(C(29)H(29)N(5))(2)](C(6)H(2)N(3)O(7))(2), consists of Cd(II) complex cations and picrate anions. In the complex cation, the Cd(II) ion is chelated by two bis-(1-allyl-benzimidazol-2-ylmeth-yl)benzyl-amine (babb) ligands in a distorted octa-hedral geometry. Extensive C-H⋯O hydrogen bonding occurs between cations and anions in the crystal structure.
متن کامل[2-(1H-Benzimidazol-2-yl-κN 3)aniline-κN]dichloridozinc
In the title benzimidazole mononuclear complex, [ZnCl(2)(C(13)H(11)N(3))], the Zn(II) ion is four-coordinated in a distorted tetra-hedral geometry by an imidazole N, an amino N and two Cl atoms. The dihedral angle between the benzimidazole and benzene rings is 9.57 (1)°. In the crystal, mol-ecules are linked by weak N-H⋯Cl hydrogen bonds into layers parallel to the bc plane. π-π inter-actions w...
متن کاملBis{1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κN 3}bis(3,5-dicarboxybenzoato-κO 1)zinc octahydrate
In the title complex, [Zn(C(9)H(5)O(6))(2)(C(11)H(10)N(4))(2)]·8H(2)O, the Zn(II) ion exhibits site symmetry 2. It shows a distorted tetra-hedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imid-azole ligands and by two O atoms from two symmetry-related monodeprotonated 3,5-dicarb-oxy-benzoate anions. In the crystal, complex mol-ecules and ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s160053681202034x